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Construction of hierarchical proton sieving-conductive channels in ...

In this work, the continuous hierarchical proton sieving-conductive channels are constructed in the ion conductive membranes through the strategy of grafting sulfated UIO-66 (UIO–66OSO3) along the polybenimidazole (PBI) backbones (Scheme 1).The sulfate ester group, with superior reactivity and acidity to the commonly used sulfonic acid group, …

Lithium ion conducting membranes for lithium-air batteries

In Li-air batteries with aqueous electrolytes (Figure 2 b and c), Li + conducting membranes becomes indispensable to separate the Li anodes and the aqueous electrolytes because the direct contact of H 2 O and Li can induce severe reactions even for a very short time.Polyplus Co., in 2004, introduced glassy ceramic membranes …

Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion ...

Engineering Polymer-Based Porous Membrane for ...

An operationally broadened alkaline water electrolyser enabled by ...

Ion-solvating membranes (ISMs) are non-porous polymer films that can uptake KOH and, therefore, conduct ions and be used as separators in electrolysers. Here the authors report an ISM for alkaline ...

Fast and Selective Ionic Transport: From Ion-Conducting Channels to Ion ...

This review discusses selective and fast transport of ionic species (ions and their associates) through systems as diverse as ion-conducting transmembrane proteins and ion exchange membranes (IEMs) in aqueous environments, with special emphasis on the role of electrostatics, specific chemical interactions, and morphology (steric effects). Contrary to …

Anionic conductive group tunable amphoteric polybenzimidazole ion ...

Anionic conductive group repels vanadium ions but is difficult to be incorporated into the selectively ionic conductive channels of the amphoteric ion conductive membrane with tunable ratio. Herein, the novel hydroxyl bromopropane anionic precursor side chain is proposed, in which the hydrophilic hydroxyl groups aggregate into …

Flexible ion-conducting membranes with 3D continuous …

Flexible ion-conducting membranes with 3D continuous nanohybrid networks for high-performance solid-state metallic lithium batteries ... was utilized to detect the thermostability of the electrolyte membranes in argon flow with a heating speed of 10 °C/min. Differential scanning calorimetry (DSC) measurements were taken using a TA …

Layered double hydroxide membrane with high hydroxide …

Layered double hydroxide membrane with high ...

Ultra-low vanadium ion permeable electrolyte membrane for vanadium ...

The trade-off between proton conduction and vanadium permeability is a great challenge for ion conductive membrane to achieve high vanadium redox flow battery (VRFB) performance. Herein, the quinone convertible phenolic hydroxyl group side chain is proposed to endow Donnan effect and continuously narrow ion conductive …

Hydrophilic microporous membranes for selective ion …

These membranes enable aqueous organic flow batteries with high energy efficiency and high capacity retention, …

Promoting ion conductivity of imidazolium grafted PVDF membranes ...

The ion conductivity of PVDF-IL membrane was only 7.54 mS/cm, while the PVDF-IL-PVP membranes showed much higher ion-conductivities than it. This result indicated that the modification by PVP could effectively promote the ion conductivity of the membranes. Additionally, with more content of PVP, the ion conductivity was enhanced …

Development of efficient aqueous organic redox flow batteries …

Aqueous organic redox flow batteries are promising for grid-scale energy storage, although their practical application is still limited. Here, the authors report highly …

Membranes and separators for redox flow batteries

Membranes and separators for redox flow batteries

Flow battery

Flow battery - Wikipedia ... Flow battery

A Chemistry and Microstructure Perspective on Ion‐Conducting Membranes ...

Redox flow batteries (RFBs) are among the most promising grid-scale energy storage technologies. However, the development of RFBs with high round-trip efficiency, high rate capability, and long cycle life for practical applications is highly restricted by the lack of appropriate ion-conducting membranes.

Transport phenomena in flow battery ion-conducting membranes

A fundamental description of ion transport in flow-battery separators can guide the development of new separators by identifying the nature of ion selectivity under …

Lithiated Nafion membrane as a single-ion conducting polymer

Lithiated Nafion membrane as a single-ion conducting ...

A sub-10 μm Ion Conducting Membrane with an Ultralow Area …

With the outstanding features of high safety, high efficiency, and long lifespan, the vanadium flow battery (VFB) is well-suited for large-scale energy storage; however, it suffers from low power density. The high ion conductivity of membranes is very important to increase the performance of VFBs at high current densities and improve their …

Composite lithium-conductive LATP+PVdF membranes: …

The commercial porous (Celgard, Daramic), ion-exchange (Nafion, Neosepta), and glass-ceramic (LiCGC) membranes, if used in non-aqueous flow batteries, suffer from poor selectivity, low ionic conductivity, insufficient chemical stability, fragility, or a high price [17], which in some cases approaches up to 50% of the total battery cost [3].

Sulfonated para‐Polybenzimidazole Membranes for Use in …

Ion conducting membranes play a crucial role in redox flow batteries, separating anolyte and catholyte while allowing proton transport to complete the circuit. However, most membranes are trapped in a trade-off relation and show either low conductivity or high vanadium crossover.

Supramolecular Sidechain Topology Mediated Pseudo

The resulting membrane endows an acidic aqueous redox flow battery with an energy efficiency of up to 80.7% even at high current densities of 220 mA cm−2, breaking the record set by the pseudo‐nanophase separation strategy constructed membranes and ranking among the highest values ever documented.